9. Angelina Jolie and Brad Pitt
Golden couple Angelina Jolie and Brad Pitt lit up the screen in 2004 with their intense magnetism on the set of the movie “Mr and Mrs Smith” Their relationship broke up Pitt’s marriage to “Friends” star Jennifer Aniston. They were married in 2014. In 2016 Jolie filed for divorce, citing “irreconcilable differences” and she has reiterated in numerous interviews that the separation was for the family’s “well being.” Jolie and Pitt share a large family of three adopted and three biological children. The divorce proceedings with multi millions at stake are still ongoing.